Hi Aviator -- Welcome to LabVIEW programming, I hope everything's working out well for you.
There's been some good discussion on doing this in the forums, so I'll send you there. However, this is going to bring in ActiveX programming (to get your hooks into Excel), and that might be yet another thing for you to learn:
https://forums.ni.com/t5/LabVIEW/How-to-write-to-a-password-protected-excel-sheet-using-ActiveX/m-p/...
In case you're not familiar with ActiveX in LabVIEW, check this link out:
https://www.ni.com/en/shop/labview/activex-and-labview.html
and from the help file:
https://www.ni.com/docs/en-US/bundle/labview/page/using-activex-with-labview.html
You can also find code examples that you can search for to manipulate Excel data from within LabVIEW with ActiveX.
Thanks and good luck!
mike