I didn't have a lot of time to play around with this but hopefully this info will be helpful.
1. First, Playing around with the ActiveX methods and properties is pretty straightforward. You just need to use invoke and property nodes to use them. The hard part is knowing what all the methods do! I found this web page which goes through all of that. Use it as a reference.
http://developer.apple.com/techpubs/quicktime/qtdevdocs/REF/QT41_HTML/QT41WhatsNew-72.html
2. I am including an example VI which shows how to open and close the application refnum and call a method using the invoke node. This is the basic pattern to use. All invoke and property nodes go in between the open and close.
Good Luck! Mostly it just takes playing around wi
th the documentation. If I get a chance I will play around with this more later.
-scraggs99