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Invoke Node: Invokes a method or action on a reference.
Property nodes let's you set functional or cosmetic properties of items, Invoke nodes have to do with actions. All this said, sometimes the use is a bit inconsistent as in the double-click items you mentioned. I'm not sure what the reason is. 😉
As with any facet of human endeavor, however, there's a gray area in which an argument can be made either way."
Qouted from: http://msdn.microsoft.com/library/default.asp?url=/library/en-us/vbcon98/html/vbconisitpropertyormet...
-Khalid