Brian,
Yes it's possible! If you are using LabView, all you have to do is call the AI Trigger Config VI and set it with range settings (Where the trigger is generated when the signal value is not between the low value and the high value).
The AI Trigger Config parameters should:
trigger type = analog trigger
mode = on
trigger or pause condition = trigger upon leaving window
level = low value in volts
additional trigger specification (window size) = high value -level
If you are using NI-DAQ function calls, the parameter would be:
mode = ND_INSIDE_REGION
Good luck with your application!