I probably won't be able to answer your question ultimately, but I can offer some help with posing your question:
1) What operating system are you running?
2) What DAQ device are you using for this?
3) What development environment (Labview, Visual Basic 6, Visual C++, Measurement Studio, etc.)?
4) 35V is pretty high- did you read the device specs to find out the maximum voltage you can apply?
5) Did you look for any example code for analog triggering?
When you post a question, you have to get outside your head and try to see the problem as someone looking in from outside. NI has a huge number of devices, and lots of different ways to program them. You have to provide basic information; this is probably why you haven't had answers.
John Weeks
WaveMetrics, Inc.
Phone (503) 620-3001
Fax (503) 620-6754
www.wavemetrics.com