You should be able to right-click on any of the functions in the library tree and select 'Function Help' to open the help documentation. If this does not work you can open the VBAXL##.chm directly which is located in the C:\Program Files\Microsoft Office\OFFICE##\1033 folder. NOTE: '##' will be specific to the version of Excel you have installed on your system. I also suggest taking a look at the 'excel2000demo' shipping example (use keyword 'excel' in the NI Example Finder) which demonstrates how to open, read, and write to an Excel file.
Have a great day,
Ecleamus Ricks, Jr. National Instruments Applications Engineer