First point to note - as already mentioned, the hex number equates to a 64 bit binary number, and it's only since LabVIEW version 8.0 that 64 bit integers are handled.
Presuming you have LV 8 then see the attached VI...
Important: You must wire a 64-bit integer to the "default" input of the "Hex to Number" function, if you want the function to return a 64-bit integer output, because otherwise it will return a 32 bit number by default (legacy from before LV handled 64 bit integers)
Mark.
P.S. If you don't have LV 8 then there would have to be more code involved to split the hex string into two parts, then convert the two parts before recombining into a 64 bit string..