Write to Spreadsheet File or now known as Write Delimited Spreadsheet.
Though it won't solve your Excel problem if you try to import too much data into Excel.
I havent heard of it but what im trying to do is to export the data so i can be able to load them into matlab, so how does diadem work
No. There are many ways to get data out of LabVIEW.
As I said, use the Write Delimited Spreadsheet function in the File I/O palette. It will write a CSV file as big as you need it, within limitations of the file system. There are other File Write functions that allow you to write out text files if you want more direct control over the data being written out.
While Diadem is an option, I don't see why you'd need it based on what you've told us so far and the fact that LabVIEW has subVI's built in that create CSV files.