The file you generate in LabVIEW is not an excel file but a simple text file...If you open such files (whether they come from LV or any other application) in Excel and then save them, Excel will by default save it as a tab delimited text file. It will pop up that warning to let you know that there might be formatting in the original document or in the new Excel document (e.g. if a formula has been added) that will be left out if it is saved as a tab delimited text file...(hinting that you may want to save it as a true Excel file instead).
If you need to open the files in Excel and want to avoid this message then you need to write a true Excel file from the start...one way to get that done is to use the report generator toolkit.