The answer to your first question depends on how you define "synchronized". If you are simply having them triggered from the same source, their sample rates can be anything you want. If you want the individual samples to be synchronized, then by definition thye must be running the same sample rate.
The way to tie two boards together is to setup a master/slave configuration where the master routes either its trigger or scan clock to the RTSI bus. The slave then uses that signal to either start its acquisition or clock the acquisition.
In terms of your other questions, the scan clock is how often each channel is sampled. The time between channel samples is defined by the interchannel delay.
There are good examples in LV on how to do this type of acquis
ition.
Mike...