I have the same configuration as you do in my computer with everything working fine, except for one thing, I have the update of LabVIEW 6.0.2, so I will recommend you three things in order to fix this issue:
1. Get the update for LabVIEW (www.ni.com >> Software Downloads >> Drivers and Updates >> Current Software Versions >> LabVIEW >> Select the update for your system, please follow all the instructions for installation. Reboot the computer after installation and try the example again.
2. Try the examples that I'm sending to you as attachment and also try the example for writing data to Excel which is located in the Help >> Examples... >> Communications >> ActiveX >> Write Table to Excel
3. Try reinstalling Excel or re-assigning the automation refn
um.
If you still found issues concerning this VI you may want to try to contact us directly and have a copy of the VI that is failing in order to test, you may find the information to reach us at www.ni.com/ask
Good luck!
Nestor Sanchez
Applications Engineer
National Instruments
Nestor