Hi,
You can simulate the NI devices to be able to debug the VI's. Follow the link from the previous post to learn more about simulated devices and how to use them. If there is any third party device being used then you will not be able to simulate it in MAX(measurement & Automation Explorer).
As for building an exe, I would copy over the configuration file separately. You do not benefit from having it included in the .exe
Make sure that your end user has all stations set up identically if you will be loading a configuration file onto all of them.
I hope this helps!
Regards,
Ima
Applications Engineer
National Instruments
LabVIEW Introduction Course - Six Hours
Getting Started with NI-DAQmx