To send your Hex data to your temperature sensor, you would just use the Serial VI's available in LabVIEW, and convert your Hex data to ASCII (string) format. There are three serial examples that ship with LabVIEW, and these will give you a good sense for how to use the Serial VI's. These examples can be found by selecting "Search Examples" from the LabVIEW splash screen, clicking on the "I/O Interfaces" link, and then on "Serial Communication."
I have attached a bitmap image to this message that shows how to use the Byte Array to String function to convert your Hex data into the string format. Good luck!