When you select Interpolation you then define a table of value pairs; basically the raw data versus actual data.
For example 2 5 4 10 6 20 ...
What the VI then does is if the input signal has a value of 3 the Express VI will linearly interpolate between 5 and 10 and will map your value of 3 to 7.5. Again a value of 5 would then be interpolated and mapped to 15.