You cannot address the instruments directly through VISA when using the GPIB-232CT-A (or GPIB/485CT-A) on Windows 2000 or XP. You would actually have to send the commands outlines in the User Manual to the converter through VISA, and those commands would direct the converter to speak to a specific instrument.
It was possible in Windows 3.1/95/98 to utilize the converter as a standard NI GPIB interface, but this was discontinued for Windows 2000/XP. With USB ports being nearly universal on modern computers, the GPIB-232CT-A is now mainly used for compatibility with existing systems which only have a serial port available--and are unlikely to be running Windows 2000 or XP.
Let us know if that helps, or if we can help answer any further questions,
Jason S.
National Instruments