You can control the power supplies if they have a GPIB interface and if you have a GPIB controller for the pc. There are LabVIEW drivers available for both of the instruments. The options for the 6632 can be found at
here and the 6642 are
here. I would recomend that you avoid the IVI drivers and stick with the either of the LabVIEW plug & play versions. The project style is for LabVIEW 8.x. If you don't have a GPIB controller, you can find one
here. You would get the necessary drivers with the controller. The GPIB and VISA drivers are also included on the LabVIEW device Drivers CD. You would need a GPIB cable for each instrument.
The 6221 is programmed with DAQmx and there are a lot of shipping examples. You should also check out the
Getting Started tutorial.