Does Measurement and Automation Explorer (MAX) detect the PCI-MIO-16E-1? MAX is software that can be used to configure all National Instruments hardware. You should have an icon on your desktop where you can launch MAX. I would suggest to open MAX and check to see if the PCI-MIO-16E-1 shows up within the devices and interfaces folder. If it doesn't, refresh MAX by pressing F5 and check the devices and interfaces folder again. Once the PCI-MIO-16E-1 is listed within MAX you should be able to use the solution wizard in LabVIEW with your DAQ hardware. I hope this helps.
Regards,
Todd D.
Applications Engineer
National Instruments