Thank you for contacting National Instruments.
One way to detect peaks is with the Waveform Peak Detection.vi. This VI finds the locations, amplitudes, and second derivatives of peaks and valleys for the input waveform signal. You can find this VI in the Analyze>>Waveform Monitoring Palette in LabVIEW, though it is not available in the Base Package of LabVIEW.
The output of interest will be the indices of the peaks found. Once you have the indices of the peaks, you can convert to time, by multiplying by your waveform dt value.
Regards,
Mike G.
National Instruments