Hey turbot,
Thanks for contacting National Instruments support. There is an example in the C:\Program Files\National Instruments\LabVIEW 8.2\examples\instr\niScope folder, or whichever version of LabVIEW you are using. The example is called niScope EX Measurement Library.vi. Within that example you can fetch an FFT measurement from the device. This is done in hardware. This also works with any Scope card.
You can fetch scalar measurements and array measurements from the device, and there are FFT spectrum measurements in both types. Let me if I can help further.
Regards,
Kenn North
Principal Product Manager - Search, Digital Analytics
http://ni.com/search