What kind of PXI controller are you using? Being able to stream to disk at those rates is very intensive on the hard drives of PXI embedded controllers. That said, I have been able to stream to disk with a PXI-8186 with 40 channels at 98kHz. This was done using a block size of 2048 and a buffer size of 102400. Also, I was writing to a single binary file. I'm not sure if or by how much writing to separate files would affect the maximum achievable rates. One thing to do is to make sure that as little as possible is happening during the streaming process (no graph displays, no processing, etc.). You may want even consider streaming in a binary format and then in post-processing, convert it to a WAV file. Just some ideas.
-Jack