Hi,
This depends mainly on what kind of data acquisition card you are using. You can find the pinouts by going to Measurement & Automation explorer and going to Help >> Help Topics >> Traditional NI-DAQ. In this document, the pinouts are listed for Traditional NI-DAQ Device Terminals >> Multifunction DAQ. It sounds like you have a 68-pin MIO board, so this lists the pinouts for the entire board.
Keep in mind, you also can also use RSE mode and get 16 channels. You would connect the V+ wire to your CH(x) and your V- wire to AIGND. Be sure to set this configuration in MAX so that you can obtain a valid reading.
Hope this helps!
Regards,
Allen P.
Applications Engineer
National Instruments