The Advanced Signal Processing Toolkit addresses PCA in the "Time
Series Analysis Tools." The following is the product page for that
toolkit, where if you click the link to "Manuals" in the "Resources"
section (highlighted in blue) you'll find the "Time Series Analysis
Tools User Manual" linked:
NI LabVIEW Advanced Signal Processing Toolkit
http://sine.ni.com/nips/cds/view/p/lang/en/nid/1395
For convenience, here is the link to the manual directly:
http://digital.ni.com/manuals.nsf/websearch/EE315092E16D3AC08625703F002356EC
Also, here is the toolkit's release document on-line:
http://digital.ni.com/worldwide/bwcontent.nsf/websearch/286eb6b494fc4a578625704a00747a85
I don't know about its particular use with your application, but this might help!
Travis M
LabVIEW R&D
National Instruments