One startup issue is how you have set the loading of the palettes. I have set it to load in the background. Also I like to mention that I have started LV from its shortcut and not by double clicking on a VI. In the later case it would load the VI and all its subVIs into memory. How long this lasts depends on the number of VIs to load and on the number of places to search for.
We are talking about a range from 5 seconds to 30 seconds which is a factor of 6. The CPU speed and RAM isn't that factor.
Waldemar
Using 7.1.1, 8.5.1, 8.6.1, 2009 on XP and RT
Don't forget to give Kudos to good answers and/or questions