If the excel file is saved as a text file - either comma or tab separated, then these functions will work. To read/write a native excel file then you have to use ActiveX or treat the excel file as a database and use the ODBC driver to interface to it. There's a shipping example that shows how to write to excel from LabVIEW and many others are available
here. To make a database query, you'll need NI's Database Connectivity Toolkit or Jeffrey Travis's open source
LabSQL.