In general, Express VIs are useful to try out new algorithms and quickly get you started. If you have an established, working algorithm, there is no real need to change it. Express VIs tend to have more overhead than hand coded routines, so if you are size or speed limited, that is something to take into account (it doesn't sound like you would have a problem). However, as I said in the first sentence, the curve fitting Express VI is a great way to try out some algorithms you haven't tried before. For example, if you know your data model is actually more complex than a quadratic, the curve fit Express VI will help you find a more suitable fit and can show you how to code it in LabVIEW, if you want to go back to a custom analysis routine.
Take home message - if you are satisfied with your current analysis, there is no reason to change. If you want to try something new, give it a try.