Hello,
I think that 6508 is simply the new name that they have given the DIO96 in DAQmx, as they are standardizing board nomenclature, so you should be able to simply choose 6508 and have your dio96 working normally.
I am attaching an image showing how you have to choose the correct version of the polymorphic VI DAQmx Write to be able to write to a single digital line instead of to a whole port.
If a VI is polymorphic, it means that you can use the same VI for different functions that require different inputs. It makes it simple, because you always use the same VI, and you simply need to choose the right settings to use it for what you need. If you don't see the polymorphic selector underneath the VI, right click on it, and put a checkmark under Visible items >> Polymorphic VI selector.
The VI on the left in the image is the DAQmx Create Channel VI, which is also polymorphic. Make sure that that VI is also set to digital, so that it does give you the option of selecting the 6508. (I suspect that the reason you don't have it available as an option to select is that the VI is set to analog input, and the 6508 cannot do analog input, so it is not an option).
Hope this helps,
Alejandro