Generally, the answer is no. Typically, when an exe is created, the block diagrams are removed and once gone, they are gone forever. Under rare circumstances, the creator of the exe will not remove the block diagrams or set it up to call an external file with the source code. Make a copy of the exe and rename it .llb. The names of the used VIs will be visible when you do a file open from LabVIEW. Open of the VIs and see if there is a block diagram. Note: LabVIEW 8.5 cannot open 5.1 files so you will need an earlier version to do this.