This seems to be more of an access problem than a labview problem, so I'm out of my depth here.
I'm not sure access supports this, but try to "DESCRIBE Pictures;". That should return a list of columns that are available. I bet you can only see the ID column.
If the other colums exist but aren't showing up then there may be some setting that's making them private. It's also possible that your labview program is accessing the wrong database. Did you ever save a version that didn't have the extra columns?
If you want to use mysql, the first thing you have to do is download it (from http://www.mysql.org/downloads/) and install it. Once it's running, you can create tables with SQL queries. I think this one will give you the table you described earlier:
CREATE TABLE `Pictures` ( `ID` int unsigned NOT NULL, `XY_graph` blob, `YZ_graph` blob, PRIMARY KEY (`ID`) );
If you do install mysql, and you've got a webserver with php, you'll probably also want phpmyadmin. It's a nice web based interface that lets you do basically everything you ever need to do to a mysql server without using the command line client. You can get it from http://www.phpmyadmin.net/.