Travis,
If you selected xlScatterLines as the chart type, the ChartWizard should automatically use the first column as your X values for all other columns. It may be that your data has the X values in the "A" column and you are not passing that column to the ChartWizard.
If you need to create a standard line chart and then convert it to an XY chart later, set each of the Chart.SeriesCollection(n).XValues to the worksheet range.
Use Worksheet Method Range to specify the block of X Values
Chart Invoke Node->SeriesCollection
Start Index input at 1
Convert SeriesCollection Variant to Type Excel.Series
Series Property Node->XValues
Change to Write
Wire in the range above
Loop thru each SeriesCollection
Michael