ping is based on messages of the ICMP protocol a low level protocol in the socket library directly related to the IP protocol part, which means below of the TCP and UDP protocols that can be accessed with the LabVIEW network primitives. The ICMP protocol is usually enabled by default although more and more servers connected directly to the internet disable it, since it can be used to send a device into overload with a targetted DOS attack.
But what is most important for you, there is no way to directly cause ping traffic in LabVIEW. Using system exec to issue the ping command on the command line is the prefered way to do that. Other means would require to access system DLLs (that are not available or not the same on all Windows versions) or directly access the socket library with some external code to get the the raw socket needed to do ICMP.
In order to use the TCP or UDP VIs you need to connect to a server application on the target that has on a specific port number a bound socket to the desired IP address, meaning the server would need to bind to both IP adresses if you want to use them at teh same time, and servers usually don't bind to more than one IP address at the same time.
Rolf Kalbermatter
Rolf Kalbermatter
My Blog 
DEMO, Electronic and Mechanical Support department, room 36.LB00.390