Hi Michael
Probably my answer is a bit late, but I think the best thing is to give it a try. I used a PCI card with the 82541 chipset (don't remember exactly which one) and it worked. But we have mainboards with an onboard 82541 chip, this doesn't work in LV 8.21 or older.
Best thing is to use a Intel PRO/100 adapter, these work for sure.
NI will improve support for ethernet chipsets, in LV 8.5 the 82541 will be supported on RT targets (we tested the beta). But I don't know whether there will be an update for 8.21.
Hope this helps,
Daniel