Hi Bernd,
The Write LVM File Express VI is a quick and easy-to-use VI that writes a tab-delimited text file that you can open with a spreadsheet application or a text-editing application. However, for better customization of the file generated, you might want to consider using some of the File I/O VIs such as Open/Create/Replace File, Write Characters to File, Write to Spreadsheet File.
I've attached an example program here that demonstrates how to write out to a spreadsheet file with column headers. Also, if you are planning on using Excel to read in your data, you can also consider using ActiveX to communicate to an Excel worksheet. I've included the shipping example that comes with LabVIEW below to this email as well.
Good luck!
Kileen C.
Applications Engineer
National Instruments