The simplest way to do this is with a precision resistor tied between either the positive or negative power supply (depending on the sense of your offset, and your input terminal. (You can also use a potentiometer, but they can be noisy unless you use an expesive film-type pot.
For small degrees of offset, you can just run your data through an ADD node in Labview, but it's always preferable to do the offset adjust in hardware, or you could end up saturating the input ("slamming it against a rail"). Look at the excellent tutorials on signal conditioning elsewhere on the Labview site.
Good Luck!
Eric
Eric P. Nichols
P.O. Box 56235
North Pole, AK 99705