If you're using V5.1 and it doesn't work with more than one NIC, upgrade. V6.0.2 running on WinNT or W2k recognizes two NIC cards transparently. You access a resource on either network and LV just finds it... I have several systems running this way.
One NIC is a corporate intranet connection that eventually ties to the outside world. I use this connection to FTP data to a central site. The other NIC is a local in-plant network that I run VIserver over. Neither connection requires any special configuration.
If you're running LV 6+ and can't get this to work, start checking the network configuration--it isn't LV's fault.
Mike...