I'm not sure exactly what you need to accomplish. If you want to actually control and run LabVIEW from Excel, I think the only way to do that is with writing a VBA macro and calling the LabVIEW ActiveX properties and methods. I couldn't find an example with VBA but maybe this Visual Basic example
here can give you some ideas. If, on the other hand, all you want to do is change some values that a LabVIEW program is using, the easiest way is to make those values changeable on the front panel of your VI or make your VI read the Excel spreadsheet. Reading an Excel spreadsheet can be done with Excel's ActiveX properties
and methods or treating the spreadsheet as a database and using ADO. One ActiveX example can be found
here. If the Excel spreadsheet is saved as a text file with comma or tab delimited data, then you can use the Read From Spreadsheet function in LabVIEW. There have numerous examples and discussions on reading Excel files posted to this forum. if you do a search, you'll find a wealth of information.