As you should have seen from the driver page, the only supported interfaces are GPIB, USB, and Ethernet. Are you sure the serial port on the scope can be used for remote control? A basic step before running any LabVIWE code is to use a program such as Hyperterminal to check com settings and cable.
If in fact the serial port works, you will probably need to modify the driver. You would also typically run the initialize function before doing anything else. Select the resource by clicking on the little arrow on the right side of the VISA resource name control. If you do that, you would be selecting only valid resources.