Which LabVIEW package do you have (Base, Full, or Professional)? If you have the base package then you will have to develop these functions on your own. If you have the full or professional packages then if you go to the Functions pallette and, under All Functions select Analyze, then select Mathematics, then select Probability and Statistics. You will find a function for Mean and for Standard Deviation on this pallette.
The built-in Mean.vi from the advanced analysis palette does not do 2D arrays, so you would need ot reshape it to a 1D array.
Of course it would be also very simple to calculate these values using plain math. The attached VI (LabVIEW 7.0) shows both possibilities (Assuming Sample weighting for the variance). Enjoy!
(Everything should also work for 3-D and higher arrays).