To plot multiple plots on the XY graph you need to create & connect an "array of plots", a plot being either...
1. A cluster of two arrrays, one array being the x-coord's, the other array being the y-coords, or...
2. A cluster wrapped array of clusters of coordinate pair points.
There is a very good (albeit visually challenging) example in the LabVIEW examples>Fundamentals>Graphs and Charts>XY Graph.vi.
One plot will always sit on top of another - the precedence is determined by the plot order (plot 0, plot 1, etc), I can't remember off-hand which way around the order is, so just find out by trial and error.
Mark H.