Hi,
I ran into the exact same Problem recently. The customer has Excel 2010 installed, I use Version 2016. LabVIEW chrashed either if I tried to save the Workbook or export it as pdf. Writing to Excel via named cells for example worked fine.
The problem here should be that Microsoft changed the ActiveX-Interface on certain methods and thats why LabVIEW chrashes.
I installed Excel 2010 on a Virtual Machine. If i have to build the .exe I will do it there. The build then worked fine on the customer's PC aswell. Another solution would be to upgrade the excel version.
Hope that helps,
Markus