If you want to create a scalable voltage value coming from the serial port you must have a Dig -> Analog conversion circuit.
If your goal is to vary a voltage from 1 - 10 vdc, then you must create:
1) a an external circuit that will convert/buffer digital serial interfaced binary values to analog values (ni makes these things)
2) labview code that transfers info to serial port. (driver/etc)
hope that helps!
did that answer your question?
Chances are if you have seen VI in the forest it hasn't fallen.