Overview
Media buttons, like play/pause, mute, etc., are not available in LabVIEWs event structure or low-level Input Device Control VIs. This is a VI that shows the method of capturing their state using .NET Keyboard class.
Inspired by this thread: http://forums.ni.com/t5/LabVIEW/Capture-Media-Keyboard-Keys/m-p/3284892
Description
See the VI.
Requirements
Software
VI made in LabVIEW 2015 SP1
Requires .NET Framework 3.0 or greater.
Hardware
Multimedia keyboard If you're using laptop, you probably have at least Mute and Volume Up/Down buttons.