Hi MrVito,
This will be specified in the documentation under the Isolation section. The PXIe-4137 will allow 250 VDC channel to ground, while the PXIe-4139 will allow 150 VDC. Note that is the maximum between any channel terminal and chassis ground. If you are floating a voltage, you need to make sure that all terminals for that channel stay below this limit.
PXIe-4137 Specifications:
http://www.ni.com/pdf/manuals/374882f.pdf
PXIe-4139 Specifications:
http://www.ni.com/pdf/manuals/376115h.pdf
Michael B.
Product Support Engineer
National Instruments