Hi bbtt,
In LabVIEW in the NI Example Finder (Help > Find Examples) there are a few different examples that can write a single line.
Once you have the Example Finder open, Browse to Hardware Input and Output > DAQmx > Digital Generation. Write Dig Chan.vi demonstates how to write values to a digital channel. Check out the Information listed on the right side of the example finder for a more in depth explanation. The vi itself also has documentation on the block diagram.
Hope this helps!
Adam W
National Instruments