Hello;
The problem there is happening because NI-DAQ version 4.9.4 doesn't support the PCI-6503 board. So, to use that board with Mac OS, you need to have the 6.6.x version. But, then, that last version only supports Labview, that explains why you are having those problems with the C interface.
Unfortunately, you will need to make a choice on what Programming Language you want to use, then choose the NI-DAQ version appropriate for that Language and board.
If you choose Labview, you can work with both cards at the same machine and install NI-DAQ 6.6.
Hope this helps.
Filipe