Since you are currently testing this chassis by itself, your VXI-MXI-2 device is considered to be the first (and only) MXI-2 controller in your system. As explained in the KnowledgeBase linked below, the logical address (LA) of the first MXI-2 controller in your system must be a power of 2 (1, 2, 4, 8, 16, 32, 64, or 128).
How Can I Configure Logical Addresses of a Multi-Chassis VXI-MXI-2 System?This explains why your single chassis does not work properly when the LA of your VXI-MXI-2 is set to 96 instead of 64 (a factor of 2). However, when you set up your multi-chassis system you should be able to use the LA of 96, as long as this is not for the first VXI-M
XI-2 controller in your system.
I hope this helps!
Best Regards,
Sonya W.
Applications Engineer
National Instruments