jcrooke,
After reading your post I don't think there is quite enough information to point you to the correct way of programming your application. Could you please post some additional information on where your sync signal will be generated (internally/externally), what device you want to source the sync signal, and any other related information that might help these forums to better assist you with your application.
In addition to posting more information, you may want to take a look at the following tutorial, which discusses NI-VXI triggering in great depth:
Triggering with NI-VXIThat tutorial may be enough to get your application headed in the right direction. If not, please post some additional information.
Best of luck with your application.
Regards,
Jed R.
Applications Engineer
National Instruments