Check out page B-2 in the SC-2345 user's manual: http://www.ni.com/pdf/manuals/371064c.pdf
You will notice that each analog input slot on the SC-2345 can output two different Nonreference Single-ended (NRSE) signals to the Data Acquisition board that is connected to the 68-pin connector at J24. If you have a SCC-AI02 connected to J1, then it has two differential analog input signals which are conditioned and passed to the DAQ board as two separate single-ended signals to channels AI0 and AI8 on the 68-pin connector. You can look up the e-series pinout with the e-series user's manual: http://digital.ni.com/manuals.nsf/websearch/05A25C65C755D8DB86256FD30081687D. You will see that AI0 and AI8 correspond to pins 68 and 34 on the 68 pin connector. Page 11 of the SCC-AI user's manual: http://www.ni.com/pdf/manuals/323089a.pdf describes the inner-workings of the module, which will also give you some additional insight into the connections.
If you are just getting started with SCC and want to know how to configure it in software, then there is an SCC quick start guide that may also be of use to you: http://digital.ni.com/manuals.nsf/websearch/5D08FA2610E23C4A86256FB1005880FA
I hope that helps.
Logan Kunitz