Hey MoparElwood,
I checked the NI High-Speed Digitizers manual and it states the following about PFI lines:
"Many NI high-speed digitizers have two digital lines that can import a trigger, import or export a reference clock, or output various signals."
The specification sheet also only discusses triggers and clocks.
http://www.ni.com/pdf/manuals/376937c.pdf
It sounds like the trigger is a good, if not the correct, approach to your situation. Why do you not want to go about the problem this way? Do you have other modules that you could use if you want to go about this a different way?
Best,
Ben