Hi,
Multisim doesn't have a photodiode, the one found in the "Rated" family was incorrectly called photodiode but it's a LED. That component was intended to work with the Phototransistor from the same family, when the diode turns on the transistor can detect it. Attached is an example how the two components work together.
Beside the Phototransistor I mentioned above, Multisim doesn't have any component that detects light. What you can use instead is a Voltage_Control_Voltage_source from the "Sources" family. The light input can be emulated with a voltage source,
Tien P.
National Instruments