This is not something I've ever tried and I can only poke around the API with a simulated X-series device.
MAX suggests that there *is* an allowable indirect routing available to push the 100 MHz timebase out to any of several PFI pins. Note: "indirect" routing generally consumes one of the counters.
The DAQmx Export Signal *Property Node* allows a few more options than the similarly named vi. None of them seem to allow an explicit specification of the 100 MHz timebase though. The best candidate I see is under Clocks->Sample Clock Timebase. To test this out, I'd make some kind of dummy task that I explicitly configured to use the 100 MHz clock as a sample clock timebase. Then I'd use the Export Signal Propety Node to try to route that sample clock timebase out to a PFI pin.
No guarantees b/c I can't check with real hardware, just describing what I'd *try*.
-Kevin P
CAUTION! New LabVIEW adopters -- it's too late for me, but you *can* save yourself. The new subscription policy for LabVIEW puts NI's hand in your wallet for the rest of your working life. Are you sure you're *that* dedicated to LabVIEW? (Summary of my reasons in this post, part of a voluminous thread of mostly complaints starting here).